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The black stains on the collar of your white shirt are likely caused by a combination of factors, including body oils, sweat, and dirt. Even if you clean your neck before wearing the shirt, these substances can still accumulate and transfer onto the fabric during wear. Here are some common reasons why this may happen:

  1. Natural Body Oils: Your skin produces natural oils that can transfer to the collar of the shirt, especially in the neck area. Over time, these oils can build up and cause discoloration on the fabric.

  2. Sweat: Sweat can also contribute to the staining of the collar. When you sweat, especially in the neck region, it can mix with the natural oils on your skin and create a more substantial residue on the fabric.

  3. Dirt and Dust: Throughout the day, you may encounter dirt, dust, and other particles in the environment. Some of these particles can settle on your skin and, subsequently, transfer to the collar of the shirt.

  4. Cosmetics and Skincare Products: If you use skincare products, lotions, or cosmetics on your neck, some of these products may transfer to the shirt collar and contribute to staining.

  5. Fabric Absorption: The collar area of shirts, especially white ones, tends to be more susceptible to staining due to its exposure to natural body oils and external factors.

To minimize the occurrence of black stains on your white shirt collar, you can try the following tips:

  1. Wash Regularly: Launder your white shirts regularly to remove accumulated oils and dirt. Follow the care instructions on the label, and consider using a pre-treatment product for collars if stains are particularly stubborn.

  2. Stain Removal Techniques: For tough stains, consider using stain removal techniques or products specifically designed for removing collar stains.

  3. Keep Your Neck Clean: Continue to clean your neck before wearing the shirt to reduce the amount of dirt and oil transferred to the collar.

  4. Avoid Overusing Skincare Products: If you use skincare products or cosmetics on your neck, try to avoid applying them right before wearing your shirt to minimize the transfer of these products to the fabric.

  5. Consider a Protective Layer: You can wear an undershirt or a collar guard, which acts as a barrier between your neck and the shirt, to protect the collar from direct contact with your skin.

Remember that over time, even with proper care, white shirts may still show signs of wear, especially in high-contact areas like collars. Being consistent with laundering and taking preventative measures can help maintain the shirt's appearance for longer periods.

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